Global warming results in more field soil suffering freeze-thaw cycles (FTCs). The environmental risk of microplastics-recognized as a global emerging contaminant-in soils undergoing FTCs remains unclear. In this study, the combined effects of FTCs and poly(butylene adipate-co-terephthalate) (PBAT) microplastics on microbial degradation of atrazine in Mollisols were investigated. Freeze-thaw cycles, rather than microplastics, significantly inhibited the biodegradation of atrazine in soil, with average inhibition ratios of 33.69% and 4.99% for FTCs and microplastics, respectively. Thawing temperature was the main factor driving the changes in soil microbial community structures and the degradation of atrazine. The degradable microplastics with an amendment level of 0.2% had different and limited effects on the dissipation of atrazine under different modes of FTCs. Among the four modes, microplastics only showed a trend toward promoting atrazine degradation under high-frequency and high-thawing-temperature FTCs. Across all modes, microplastics altered microbial interactions and ecological niches that included affecting specific bacterial abundance, module keystone species, microbial network complexity, and functional genes in soil. There's no synergistic effect between microplastics and FTCs on the degradation of atrazine in soil within a short-term period. This study provides critical insights into the ecological effects of the new biodegradable mulch film-derived microplastics in soil under FTCs.

The freeze-thaw erosion zone of the Tibetan Plateau (FTZTP) maintains an ecologically fragile system with enhanced thermal sensitivity under climate warming. Vegetation phenology in this cryosphere-dominated environment acts as a crucial biophysical indicator of climate variability, showing potentially amplified responses to environmental changes relative to other ecosystems. To investigate vegetation phenological characteristics and their climate responses, we derived key phenological parameters (the start, end and length of growing season-SOS, EOS, LOS) for the FTZTP from 2001 to 2021 using MODIS EVI data and analysed their spatiotemporal patterns and climatic drivers. Results indicated that the spatial distribution of phenology was highly heterogeneous, influenced by local climate, complex topography and diverse vegetation. SOS generally exhibited a delayed trend from east to west, while EOS was progressively later from the central plateau towards the southeast and southwest. Consequently, LOS shortened along both east-west and south-north gradients. Under sustained warming and wetting, the region experienced intensified freeze-thaw cycles, characterised by a delayed freeze-start, advanced thaw-end and shortened freeze-thaw duration. Both climate warming and freeze-thaw changes drove an overall significant advancement of SOS (-3.1 days/decade), delay of EOS (+2.2 days/decade) and extension of LOS (+5.3 days/decade) over the 21-year period. Notably, an abrupt phenological shift occurred around 2015. Prior to 2015, both SOS and EOS advanced, whereas afterward, SOS transitioned to a delaying trend and EOS exhibited a markedly stronger delay, leading to a pronounced extension of LOS. This regime shift was primarily attributed to changes in hydrothermal conditions controlled by climate warming and evolving freeze-thaw dynamics, with temperature being the dominant factor and precipitation exerting seasonally differential effects. Our findings elucidate the complex responses of alpine cryospheric ecosystems to climate change, revealing freeze-thaw processes as a key modulator of vegetation phenology.

To investigate the coupled time effects of root reinforcement and wet-dry deterioration in herbaceous plant-loess composites, as well as their microscopic mechanisms, this study focused on alfalfa root-loess composites at different growth stages cultivated under controlled conditions. The research included measuring root morphological parameters, conducting wet-dry cycling tests, and performing triaxial compression tests and microscopic analyses (CT scanning and nuclear magnetic resonance) on both bare loess and root-loess composites under various wet-dry cycling conditions. By obtaining shear strength parameters and microstructural indices, the study analyzed the temporal evolution of the shear strength and microstructural characteristics of root-loess composites under wet-dry cycling. The findings indicated that the alfalfa root-loess composite effective cohesion was significantly higher than that of the plain soil in the same growth stage. The alfalfa root-loess composite effective cohesion increased during the growth stage in the same dry-wet cycles. The alfalfa root-loess composite effective cohesion in the same growth stage was negatively correlated with the number of dry-wet cycles. The fatigue damage of the soil's microstructure (pore coarsening, cement hydrolysis, and crack development) increased continuously with the number of dry-wet cycles. However, due to the difference in mechanical properties between roots and the soil, the root-soil composite prevented the deterioration of the soil matrix strength by the dry-wet cycles. As the herbaceous plants grow, the time effect observed in the shear strength of the root-soil composite under the action of dry-wet cycles is the result of the interaction and dynamic coordination between the soil-stabilizing function of the herbaceous plant roots and the deterioration caused by drywet cycles.

Uneven displacement of permafrost has become a major concern in cold regions, particularly under repeated freezing-thawing cycles. This issue poses a significant geohazard, jeopardizing the safety of transportation infrastructure. Statistical analyses of thermal penetration suggest that the problem is likely to intensify as water erosion expands, with increasing occurrences of uneven displacement. To tackle the challenges related to mechanical behavior under cyclic loading, the New Geocell Soil System has been implemented to mitigate hydrothermal effects. Assessment results indicate that the New Geocell Soil System is stable and effective, offering advantages in controlling weak zones on connecting slopes and reducing uneven solar radiation. Consequently, the New Geocell Soil System provides valuable insights into the quality of embankments and ensures operational safety by maintaining displacement at an even level below 1.0 mm. The thermal gradient is positive, with displacement below 6 degrees C/m, serving as a framework for understanding the stability of the subgrade. This system also enhances stress and release the sealing phenomenon.

Freeze-thaw cycles (FTC) influence soil erodibility (K-r) by altering soil properties. In seasonally frozen regions, the coupling mechanisms between FTC and water erosion obscure the roles of FTC in determining soil erosion resistance. This study combined FTC simulation with water erosion tests to investigate the erosion response mechanisms and key drivers for loess with varying textures. The FTC significantly changed the mechanical and physicochemical characteristics of five loess types (P < 0.05), especially reducing shear strength, cohesion, and internal friction angle, with sandy loam exhibiting more severe deterioration than silt loam. Physicochemical indices showed weaker sensitivity to FTC versus mechanical properties, with coefficients of variation below 5 %. Wuzhong sandy loess retained the highest K-r post-FTC, exceeding that of the others by 1.04 similar to 2.25 times, highlighting the dominant role of texture (21.37 % contribution). Under different initial soil moisture contents (SMC), K-r increased initially and then stabilized with successive FTC, with a threshold effect of FTC on K-r at approximately 10 FTC. Under FTC, the K-r variation rate showed a concave trend with SMC, turning point at 12 % SMC, indicating that SMC regulates freeze-thaw damage. Critical shear stress exhibited an inverse response to FTC compared to K-r, displaying lower sensitivity. The established K-r prediction model achieved high accuracy (R-2 = 0.87, NSE = 0.86), though further validation is required beyond the design conditions. Future research should integrate laboratory and field experiments to expand model applicability. This study lays a theoretical foundation for research on soil erosion dynamics in freeze-thaw-affected areas.

Expansive soil, characterized by significant swelling-shrinkage behavior, is prone to cracking under wet-dry cycles, severely compromising engineering stability. This study combines experimental and molecular dynamics (MD) simulation approaches to systematically investigate the improvement effects and micromechanisms of polyvinyl alcohol (PVA) on expansive soil. First, direct shear tests were conducted to analyze the effects of PVA content (0 %-4 %) and moisture content (30 %-50 %) on the shear strength, cohesive force, and internal friction angle of modified soil. Results show that PVA significantly enhances soil cohesive force, with optimal improvement achieved at 3 % PVA content. Second, wet-dry cycle experiments revealed that PVA effectively suppresses crack propagation by improving tensile strength and water retention. Finally, molecular dynamics simulations uncovered the distribution of PVA between montmorillonite (MMT) layers and its influence on interfacial friction behavior. The simulations demonstrated that PVA forms hydrogen bonding networks, enhancing interlayer interactions and frictional resistance. The improved mechanical performance of PVAmodified soil is attributed to both nanoscale bonding effects and macroscale structural reinforcement. This study provides theoretical insights and technical support for expansive soil stabilization.

This study investigates the microhardness and geometric degradation mechanisms of interfacial transition zones (ITZs) in recycled aggregate concrete (RAC) exposed to saline soil attack, focusing on the influence of supplementary cementitious materials (SCMs). Ten RAC mixtures incorporating fly ash (FA), granulated blast furnace slag (GBFS), silica fume (SF), and metakaolin (MK) at 10 %, 15 %, and 20 % replacement ratios were subjected to 180 dry-wet cycles in a 7.5 %MgSO4-7.5 %Na2SO4-5 %NaCl solution. Key results reveal that ITZ's microhardness and geometric degradation decreases with exposure depth but intensifies with prolonged dry-wet cycles. The FAGBFS synergistically enhances ITZ microhardness while minimizing geometric deterioration, with ITZ's width and porosity reduced to 67.6-69.0 mu m and 25.83 %, respectively. In contrast, FA-SF and FA-MK exacerbate microhardness degradation, increasing porosity and amplifying microcrack coalescence. FA-GBFS mitigates the diffusion-leaching of aggressive/original ions and suppresses the formation of corrosion products, thereby inhibiting the initiation and propagation of microcracks. In contrast, FA-SF and FA-MK promote the formation of ettringite/gypsum and crystallization bloedite/glauberite, which facilitates the formation of trunk-limb-twig cracks.

In recent years, excessive accumulations of iron (Fe), manganese (Mn), and nitrogen (N) have been observed in the groundwater of agricultural regions, particularly in flood irrigation areas. Nevertheless, the causes of this phenomenon and the associated hydrobiogeochemical processes remain elusive. This study demonstrated that redox fluctuations instigated by flood irrigation triggered a synergistic interaction between the N cycles and the activation of Fe and Mn oxides, thereby resulting in elevated concentrations of Fe, Mn, and N simultaneously. Static experiments revealed that the properties of the topsoil exerted a profound influence on the N induced release of Fe and Mn. The black soil (TFe: 1.5-2.3 times, Mn(II): 1.1-1.5 times, nitrate: 1.3-1.4 times) had greater release potential than meadow and dark brown soils due to higher electron donors/acceptors and substrates. Dynamic column experiments further elucidated that the wet-dry cycles induced by agricultural cultivation regulated the release process through the formation of zonal redox gradients and the structuring of microbial community. Organic nitrogen mineralization, chemolithotrophic nitrification, and Feammox/Mnammox were identified as the primary mechanisms responsible for the reductive dissolution of Fe-Mn oxides. On the other hand, autotrophic denitrification, with nitrate serving as the electron acceptor, constituted the main process for the reoxidation of Fe and Mn. Furthermore, the agricultural activities exerted a significant impact on the nitrate attenuation process, ultimately resulting in the recurrence of TFe (black soil: 1.5-6.3 times) and nitrate (black soil: 1.4-1.6 times) pollution during the phase after harvesting of rice (days 40-45) in saturated zone. The findings of this study not only deepened the understanding of the intricate interactions and coupled cycles between primary geochemical compositions and anthropogenic pollutants, but also provided a scientific foundation for the effective management and prevention of groundwater pollution stemming from agricultural cultivation processes.

As a result of the research performed, the emission of CO2 from soils in the southern tundra ecosystems of the northeastern Russian Plain has been estimated using the example of the environs of Vorkuta. The soil cover of the studied area is presented by Histic Turbic Cryosol, Histic Reductaquic Glacic Cryosol, Reductaquic Glacic Cryosol, and Reductaquic Glacic Cryosol. Atypically high values of CO2 emission from soils [2.13 +/- 0.13 g C/(m2 day)] were largely due to the weather of the 2022 growing season: high air temperatures and low precipitation. About 60% of the variability in the emission value was due to the content of microbial biomass carbon and extractable soil carbon, temperature, and soil moisture. High spatial variation in the content of extractable carbon and microbial biomass carbon and parameters of hydrothermal regime of soils was found. The soils were characterized by low values of extractable organic carbon and soil microbial biomass carbon (224 +/- 18 and 873 +/- 73 mg C/kg of soil, respectively). The thickness of organic horizon of soil determines 72% of variability in the content of microbial biomass carbon and 79% of variability in the content of extractable carbon. Regular measurements of CO2 emissions from soils of tundra ecosystems in the northeast of the Russian Plain should obtain special attention, as this will improve the accuracy of assessing the global greenhouse gas flows.

Soil chemical washing has the disadvantages of long reaction time, slow reaction rate and unstable effect. Thus, there is an urgent need to find a cost-effective and widely applicable alternative power to facilitate the migration of washing solutions in the soil, so as to achieve efficient removal of heavy metals, reduce the risk of soil compaction, and mitigate the damage of soil structure. Therefore, the study used a combination of freeze-thaw cycle (FTC) and chemical washing to obtain three-dimensional images of soil pore structure using micro-X-ray microtomography, and applied image analysis techniques to study the effects of freeze-thaw washing on the characteristics of different pore structures of the soil, and then revealed the effects of pore structure on the removal of heavy metals. The results showed that the soil pore structure of the freeze-thaw washing treatment (FT) became more porous and complex, which increased the soil imaged porosity (TIP), pore number (TNP), porosity of macropores and irregular pores, permeability, and heavy metal removal rate. Macroporosity, fractal dimension, and TNP were the main factors contributing to the increase in TIP between treatments. The porous structure resulted in larger effective pore diameters, which contain a greater number of branching pathways and pore networks, allowing the chemical washing solutions to fully contact the soil, increasing the roughness of the soil particle surface, mitigating the risk of soil compaction, and decreasing the contamination of heavy metals. The results of this study contribute to provide new insights into the management of heavy metal pollution in agricultural soils.