Permafrost soils contain approximately twice the amount of carbon as the atmosphere and this carbon could be released with Arctic warming, further impacting climate. Mosses are major component of Arctic tundra ecosystems, but the environmental drivers controlling heat penetration though the moss layer and into the soil and permafrost are still debated, especially at fine spatial scales where microtopography impacts both vegetation and soil moisture. This study measured soil temperature profiles (1-15 cm), summer thaw depth, water table depth, soil moisture, and moss thickness at a fine spatial scale (2 m) together with meteorological variables to identify the most important controls on the development of the thaw depth during two Arctic summers. We found a negative relationship between the green moss thickness (up to 3 cm) and the soil temperatures at 15 cm, suggesting that mosses insulated the soil even at high volumetric water contents (>70%) in the top 5 cm. A drier top (2-3 cm) green moss layer better insulated deep (15 cm) soil layers by reducing soil thermal conductivity, even if the moss layers immediately below the top layer were saturated. The thickness of the top green moss layer had the strongest relationships with deeper soil temperatures, suggesting that the top layer had the most relevant role in regulating heat transfer into deeper soils. Further drying of the top green moss layer could better insulate the soil and prevent permafrost thawing, representing a negative feedback on climate warming, but damage or loss of the moss layer due to drought or fire could reduce its insulating effects and release carbon stored in the permafrost, representing a positive feedback to climate warming.

The thermal stability of permafrost, a foundation for engineering infrastructure in cold regions, is increasingly threatened by the dual stressors of climate change and anthropogenic disturbance. This study investigates the dynamics of the crushed rock revetted embankment at the Kunlun Mountain Section of the Qinghai-Tibet Railway, systematically investigating the coupled impacts of climate warming and engineering activities on permafrost thermal stability using borehole temperature monitoring data (2008-2024) and climatic parameter analysis. Results show that under climate-driven effects, the study area experienced an air temperature increase of 0.2 degrees C per decade over the 2015-2024. Concurrently, the mean annual air thawing degree-days (TDD) rose by 13.8 degrees C center dot d/a, leading to active-layer thickening at a rate of 3.8 cm center dot a- 1at natural ground sites. From 2008 to 2024, the active layer had thickened by 0.7-0.8 m. At the embankment toe (BH 5), the active-layer thickening rate (3.3 cm center dot a- 1) was 25 % lower than that at the natural ground borehole (3.8 cm center dot a- 1); correspondingly, the underlying permafrost temperature increase rate at the toe (0.3 degrees C per decade) was lower than that at the natural borehole (0.5-0.6 degrees C per decade). Permafrost warming rates decreased with depth. Shallow layers (above -2 m) were significantly influenced by climate, with warming rates of 0.3-0.6 degrees C per decade. In contrast, deep layers (below -10 m) showed warming rates converging with the background atmospheric temperature trend (0.2 degrees C per decade). Thermal regime disturbance was most pronounced at horizontal distances of 3.0-5.0 m from the embankment. Nevertheless, the crushed-rock revetment maintained a permafrost table 0.6 m shallower than that of natural ground, confirming its thermal diode effect (facilitating convective cooling in winter), which partially offset climate warming impacts. This study provides critical empirical data and validates the cooling mechanism of crushed-rock revetment, which is essential for predicting the long-term thermal stability and informing adaptive maintenance strategies for railway infrastructure in warming permafrost regions.

The Three-Rivers Headwater Region (TRHR) is located on the Tibetan Plateau, within a transitional zone between seasonally frozen ground and continuous permafrost. Over 70 % of the region is predominantly covered by alpine grasslands, a vulnerable ecosystem increasingly threatened by ongoing permafrost degradation. This study utilized satellite data to analyze permafrost degradation by measuring active layer thickness (ALT) and the soil non-frozen period (NFP), and to investigate their impacts on alpine grassland growth. Results showed significant permafrost degradation from 2000 to 2020, with ALT thickening at a rate of 7.79 cm/decade (p < 0.05) and NFP lengthening by 1.1 days/yr (p < 0.05). Simultaneously, grassland vegetation exhibited a significant greening trend (0.0014 yr(-1), p < 0.01). Using the partial least squares (PLS) regression method, the study evaluated the relationships between grassland dynamics and permafrost degradation, while jointly accounting for climate variables (temperature, precipitation, and sunshine duration). ALT thickening was the dominant explanatory variable for grassland growth in 11.09 % of the region, and it was positively correlated in relatively cold western and alpine areas, but negatively correlated in the relatively warm eastern and central regions. NFP extension was the dominant explanatory variable for grassland growth in 10.38 % of the region, although its positive correlation weakened as climate conditions transitioned from relatively cold-dry to relatively warm-wet. Although permafrost degradation was positively correlated with grassland greening in relatively cold regions, the diminishing benefit of NFP extension and the adverse effects of ALT thickening may increasingly undermine grassland stability in relatively warm regions under further climate warming.

The morphology of sheep wool applied as organic fertilizer biodegraded in the soil was examined. The investigations were conducted in natural conditions for unwashed waste wool, which was rejected during sorting and then chopped into short segments and wool pellets. Different types of wool were mixed with soil and buried in experimental plots. The wool samples were periodically taken and analyzed for one year using Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS). During examinations, the changes in the fibers' morphology were observed. It was stated that cut wool and pellet are mechanically damaged, which significantly accelerates wool biodegradation and quickly destroys the whole fiber structure. On the contrary, for undamaged fibers biodegradation occurs slowly, layer by layer, in a predictable sequence. This finding has practical implications for the use of wool as an organic fertilizer, suggesting that the method of preparation can influence its biodegradation rate. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SEM)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(EDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Central and Eastern European geography, shaped by its entanglement of natural and social sciences, provides a distinctive lens for rethinking the unity of the discipline. Its historical and institutional hybridity makes the region particularly well positioned to foster integrative geographical perspectives. The objective of this study was to evaluate the present, post-transitional state of the discipline in Central and Eastern Europe (CEE), to identify its future trajectory and to uncover the significant role of CEE geography in addressing global environmental, social and economic challenges. To facilitate this process, four significant geographical topics have been identified as potentially providing a conducive environment for the partial reintegration of geography. The aforementioned themes encompass a range of topics, including migrations, the green transition, anthropogenic climate change, global tipping points, wetland disturbance, peatland carbon sequestration and cryosphere degradation. Furthermore, we have sought to assess the perspective and significance of geographical unity in addressing global crises that impact human life on Earth. This analysis has enabled the identification of critical issues that necessitate integrated approaches. The necessity for enhanced collaboration between physical and human geography, as well as between nature studies and social and economic explorations, is emphasised. In this regard, it is acknowledged that a more inclusive approach is employed in the field of CEE geography, with contributions from other disciplines such as biology, ecology, physics, sociology and economics being welcomed. These disciplines address processes that span from local to global scales, as well as those that study long-term phenomena, such as history and archaeology. The establishment of robust interdisciplinary networks has the potential to enhance the scientific standing of integrated geography and to strengthen innovative connections between human and physical geography.

Correlations between the mechanical properties and surface scratch resistance of polylactic acid (PLA) are investigated via tensile and scratch tests on samples after degradation in soil for various times. The results show that the tensile yield strength of PLA is inversely proportional to the natural logarithm of the degradation time, and the scratch resistance and fracture toughness of PLA and the temperature rise near the indenter all increase and then decrease. The surface crystallinity of PLA also increases and then decreases, indicating that it and the scratch resistance are closely related. These findings provide useful information about how PLA behaves under degradation conditions. (c) 2025 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC) license (https://creativecommons.org/licenses/by-nc/4.0/).

Understanding soil organic carbon (SOC) distribution and its environmental controls in permafrost regions is essential for achieving carbon neutrality and mitigating climate change. This study examines the spatial pattern of SOC and its drivers in the Headwater Area of the Yellow River (HAYR), northeastern Qinghai-Xizang Plateau (QXP), a region highly susceptible to permafrost degradation. Field investigations at topsoils of 86 sites over three summers (2021-2023) provided data on SOC, vegetation structure, and soil properties. Moreover, the spatial distribution of key permafrost parameters was simulated: temperature at the top of permafrost (TTOP), active layer thickness (ALT), and maximum seasonal freezing depth (MSFD) using the TTOP model and Stefan Equation. Results reveal a distinct latitudinal SOC gradient (high south, low north), primarily mediated by vegetation structure, soil properties, and permafrost parameters. Vegetation coverage and above-ground biomass showed positive correlation with SOC, while soil bulk density (SBD) exhibited a negative correlation. Climate warming trends resulted in increased ALT and TTOP. Random Forest analysis identified SBD as the most important predictor of SOC variability, which explains 38.20% of the variance, followed by ALT and vegetation coverage. These findings likely enhance the understanding of carbon storage controls in vulnerable alpine permafrost ecosystems and provide insights to mitigate carbon release under climate change.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Global warming results in more field soil suffering freeze-thaw cycles (FTCs). The environmental risk of microplastics-recognized as a global emerging contaminant-in soils undergoing FTCs remains unclear. In this study, the combined effects of FTCs and poly(butylene adipate-co-terephthalate) (PBAT) microplastics on microbial degradation of atrazine in Mollisols were investigated. Freeze-thaw cycles, rather than microplastics, significantly inhibited the biodegradation of atrazine in soil, with average inhibition ratios of 33.69% and 4.99% for FTCs and microplastics, respectively. Thawing temperature was the main factor driving the changes in soil microbial community structures and the degradation of atrazine. The degradable microplastics with an amendment level of 0.2% had different and limited effects on the dissipation of atrazine under different modes of FTCs. Among the four modes, microplastics only showed a trend toward promoting atrazine degradation under high-frequency and high-thawing-temperature FTCs. Across all modes, microplastics altered microbial interactions and ecological niches that included affecting specific bacterial abundance, module keystone species, microbial network complexity, and functional genes in soil. There's no synergistic effect between microplastics and FTCs on the degradation of atrazine in soil within a short-term period. This study provides critical insights into the ecological effects of the new biodegradable mulch film-derived microplastics in soil under FTCs.

Aeolian sand, as a primary medium of desertification, changes surface energy budgets and consequently affects both ecological systems and infrastructure stability on the Tibetan Plateau. Accurate interpretation of upper boundary conditions is critical for assessing aeolian sand's effects on subsurface hydrothermal processes. Nevertheless, current numerical simulations typically rely on empirical thermal boundaries and neglect surface radiation components and latent heat exchange, causing, significant deviations between simulations and field observations. This study establishes a thermal boundary model to calculate net surface energy (Q) based on energy balance theory and 13 sets of reflectance experiments. Using meteorological data from 2003 to 2019, soil temperature evolution was simulated under three aeolian sand coverage conditions: dry, 5 % moisture, and 10 % moisture. Results indicated that the simulated outputs exhibit strong correlations with observed data in terms of trend direction, phase timing of peaks and troughs, and temperature amplitude (R > 0.93, p < 0.0001). At the sand-atmosphere interface (-0.05 m), the annual mean temperature under dry aeolian sand cover reached 5.300 degrees C, which is 4.823 degrees C higher than that of the exposed surface (0.477 degrees C) during 2005-2006. When including moisture, the latent heat-driven cooling effect became evident, and the annual mean temperature at the sand surface dropped significantly to 0.930 degrees C (5 % moisture) and 1.461 degrees C (10 % moisture). More importantly, moisture cooling effects in shallow layers (-0.05 to-0.4 m) exhibit non-monotonic behavior: 10 % moisture yields higher annual mean temperatures than 5 % moisture (e.g., 1.370 degrees C vs. 0.858 degrees C at-0.2 m), suggesting aeolian sand's thermal impact on underlying permafrost involves critical moisture thresholds.