Substantial nitrous oxide (N2O) emissions from permafrost-affected regions could accelerate climate warming, given that N2O exhibits approximately 300 times greater radiative forcing potential than carbon dioxide. Pronounced differences exist in N2O emissions between freeze and thaw periods (FP and TP), but the mechanisms by which environmental factors regulate the production and emission of N2O during these two periods have not been thoroughly examined. We therefore combined static chamber gas chromatography, in-situ soil temperature (ST) and moisture (SM) monitoring, and 16S rRNA sequencing to investigate seasonal N2O variations in the Qinghai-Tibet Plateau (QTP) alpine meadow ecosystem, and assess the relative contributions of environmental and microbial drivers. Our findings indicate that N2O fluxes (-3.15 to 6.10 mu g m-2 h-1) fluctuated between weak sources and sinks, peaking during FP, particularly at its late stage with initial surface soil thawing. Soil properties affect N2O emissions by regulating denitrification processes and altering microbial community diversity. During the FP, ST fluctuations control N2O release by modifying mineral nutrient availability. During TP, soil texture modulates denitrification-driven N2O production through its effect on SM. Spring N2O pulses likely originate from microbial reactivation in thawed soil. N2O accumulated in frozen soil may gradually release during vertical profile thawing. On the QTP, a warmer and wetter climate scenario may alter N2O emissions by modifying the duration of the FP and TP and phase-specific hydrothermal allocation. This study provides mechanistic insights for predicting climate change impacts on N2O flux in fragile alpine meadow ecosystems.

This research explores the stabilization of clay soil through the application of geopolymer binder derived from silicomanganese slag (SiMnS) and activated by sodium hydroxide (NaOH). This research aims to evaluate the effects of key parameters, including the percentage of slag, the activator-to-stabilizer ratio, and curing conditions (time and temperature), on the mechanical properties of the stabilized soil. Unconfined compressive strength (UCS) tests were conducted to assess improvements in soil strength, while scanning electron microscopy (SEM) was employed to analyze the microstructural changes and stabilization mechanisms. The results demonstrated that clay soil stabilized with SiMnS-based geopolymers exhibited significant strength enhancement. Specifically, the sample stabilized with 20% SiMnS and an activator-to-slag ratio of 1.6, cured at room temperature for 90 days, achieved a UCS of 27.03 kg & frasl;cm2. The uniaxial strength was found to be positively correlated with the SiMnS content, activator ratio, curing time, and temperature. Additionally, the strain at failure remained below 1.5% for all samples, indicating a marked improvement in soil stiffness. SEM analysis revealed that geopolymerization led to the formation of a dense matrix, enhancing soil particle bonding and overall durability. These results emphasize the potential of SiMnS-based geopolymers as a sustainable and effective soil stabilizer for geotechnical applications.

Expansive soil, characterized by significant swelling-shrinkage behavior, is prone to cracking under wet-dry cycles, severely compromising engineering stability. This study combines experimental and molecular dynamics (MD) simulation approaches to systematically investigate the improvement effects and micromechanisms of polyvinyl alcohol (PVA) on expansive soil. First, direct shear tests were conducted to analyze the effects of PVA content (0 %-4 %) and moisture content (30 %-50 %) on the shear strength, cohesive force, and internal friction angle of modified soil. Results show that PVA significantly enhances soil cohesive force, with optimal improvement achieved at 3 % PVA content. Second, wet-dry cycle experiments revealed that PVA effectively suppresses crack propagation by improving tensile strength and water retention. Finally, molecular dynamics simulations uncovered the distribution of PVA between montmorillonite (MMT) layers and its influence on interfacial friction behavior. The simulations demonstrated that PVA forms hydrogen bonding networks, enhancing interlayer interactions and frictional resistance. The improved mechanical performance of PVAmodified soil is attributed to both nanoscale bonding effects and macroscale structural reinforcement. This study provides theoretical insights and technical support for expansive soil stabilization.

Shallow cut-and-cover underground structures, such as subway stations, are traditionally designed as rigid boxes (moment-resisting connections between the main structural members), seeking internal hyperstaticity and high lateral (transverse) stiffness to achieve important seismic capacity. However, since seismic ground motions impose racking drifts, this proved rather prejudicial, with great structural damage and little resilience. Therefore, two previous papers proposed an opposite strategy seeking low lateral (transverse) stiffness by connecting the structural elements flexibly (hinging and sliding). Under severe seismic inputs, these structures would accommodate racking without significant damage; this behaviour is highly resilient. The seismic resilience of this solution was numerically demonstrated in the well-known Daikai station (Kobe, Japan) and a station located in Chengdu (China). This paper is a continuation of these studies; it aims to extend, deepen, and ground this conclusion by performing a numerical parametric study on these two stations in a wide and representative set of situations characterised by the soil type, overburden depth, engineering bedrock position, and high- and lowlateral-stiffness of the stations. The performance indices are the racking displacement and the structural damage (quantified through concrete damage variables). The findings of this study validate the previous remarks and provide new insights.

Permafrost thaw and thermokarst development pose urgent challenges to Arctic communities, threatening infrastructure and essential services. This study examines the reciprocal impacts of permafrost degradation and infrastructure in Point Lay (Kali), Alaska, drawing on field data from similar to 60 boreholes, measured and modeled ground temperature records, remote sensing analysis, and community interviews. Field campaigns from 2022-2024 reveal widespread thermokarst development and ground subsidence driven by the thaw of ice-rich permafrost. Borehole analysis confirms excess-ice contents averaging similar to 40%, with syngenetic ice wedges extending over 12 m deep. Measured and modeled ground temperature data indicate a warming trend, with increasing mean annual ground temperatures and active layer thickness (ALT). Since 1949, modeled ALTs have generally deepened, with a marked shift toward consistently thicker ALTs in the 21st century. Remote sensing shows ice wedge thermokarst expanded from 60% in developed areas by 2019, with thaw rates increasing tenfold between 1974 and 2019. In contrast, adjacent, undisturbed tundra exhibited more consistent thermokarst expansion (similar to 0.2% yr(-1)), underscoring the amplifying role of infrastructure, surface disturbance, and climate change. Community interviews reveal the lived consequences of permafrost degradation, including structural damage to homes, failing utilities, and growing dependence on alternative water and wastewater strategies. Engineering recommendations include deeper pile foundations, targeted ice wedge stabilization, aboveground utilities, enhanced snow management strategies, and improved drainage to mitigate ongoing infrastructure issues. As climate change accelerates permafrost thaw across the Arctic, this study highlights the need for integrated, community-driven adaptation strategies that blend geocryological research, engineering solutions, and local and Indigenous knowledge.

Forests are increasingly impacted by climate change, affecting tree growth and carbon sequestration. Tree-ring width, closely related to tree growth, is a key climate proxy, yet models describing ring width or growth often lack comprehensive environmental data. This study assesses ERA5-Land data for tree-ring width prediction compared to automatic weather station observations, emphasizing the value of extended and global climate data. We analyzed 723 site-averaged and detrended tree-ring chronologies from two broadleaved and two gymnosperm species across Europe, integrating them with ERA5-Land climate data, CO2 concentration, and a drought index (SPEI12). A subset was compared with weather station data. For modelling interannual variations of tree-ring width we used linear models to assess parameter importance. ERA5-Land and weather-station-based models performed similarly, maintaining stable correlations and consistent errors. Models based on meteorological data from weather stations highlighted SPEI12, sunshine duration, and temperature extremes, while ERA5-Land models emphasized SPEI12, dew-point temperature (humidity), and total precipitation. CO2 positively influenced the growth of gymnosperm species. ERA5-Land facilitated broader spatial analysis and incorporated additional factors like evaporation, snow cover, and soil moisture. Monthly assessments revealed the importance of parameters for each species. Our findings confirm that ERA5-Land is a reliable alternative for modeling tree growth, offering new insights into climate-vegetation interactions. The ready availability of underutilized parameters, such as air humidity, soil moisture and temperature, and runoff, enables their inclusion in future growth models. Using ERA5-Land can therefore deepen our understanding of forest responses to diverse environmental drivers on a global scale.

Soil-plant-atmosphere interaction (SPAI) plays a significant role on the safety and serviceably of geotechnical infrastructure. The mechanical and hydraulic soil behaviour varies with the soil water content and pore water pressures (PWP), which are in turn affected by vegetation and weather conditions. Focusing on the hydraulic reinforcement that extraction of water through the plant roots offers, this study couples advances in ecohydrological modelling with advances in geotechnical modelling, overcoming previous crude assumptions around the application of climatic effects on the geotechnical analysis. A methodology for incorporating realistic ecohydrological effects in the geotechnical analysis is developed and validated, and applied in the case study of a cut slope in Newbury, UK, for which field monitoring data is available, to demonstrate its successful applicability in boundary value problems. The results demonstrate the positive effect of vegetation on the infrastructure by increasing the Factor of Safety. Finally, the effect of climate change and changes in slope vegetation cover are investigated. The analysis results demonstrate that slope behaviour depends on complex interactions between the climate and the soil hydraulic properties and cannot be solely anticipated based on climate data, but suctions and changes in suction need necessarily to be considered.

Predictive modeling of dielectric heating in porous foods is challenging due to their nature as multiphase materials. To explore the relationship between the topological structure of multiphase foods and the accuracy of dielectric mixture models, the degree of anisotropy of two cooked rice samples with 26 and 32 % porosity was determined, and their dielectric properties were estimated using the Lichtenecker (LK), Landau-LifshitzLooyenga (LLL), and Complex Refractive Index Mixture (CRIM) equations. These properties were used in a predictive finite-element model for reheating an apparent homogeneous rice sample on a flatbed microwave (MW) for 120 s. The results were compared with experimental data and a validated two-element model. Unlike LK and LLL equations, the CRIM equation predicted heat accumulation towards the edges of the container at the two values of porosity ratio evaluated, in accordance with the experimental results and the isotropic nature of the sample. The simulated temperature distributions suggest that the three evaluated equations could predict the MW heating behavior of rice to some extent, but that in order to obtain more accurate results, it could be useful to obtain an empirical topology-related parameter specific for this sample. These results can provide insight on the relationship between the topology of the porous structure in the sample and the adequacy of different dielectric mixture models.

Land surface temperature (LST) plays an important role in Earth energy balance and water/carbon cycle processes and is recognized as an Essential Climate Variable (ECV) and an Essential Agricultural Variable (EAV). LST products that are issued from satellite observations mostly depict landscape-scale temperature due to their generally large footprint. This means that a pixel-based temperature integrates over various components, whereas temperature individual components are better suited for the purpose of evapotranspiration estimation, crop growth assessment, drought monitoring, etc. Thus, disentangling soil and vegetation temperatures is a real matter of concern. Moreover, most satellite-based LSTs are contaminated by directional effects due to the inherent anisotropy properties of most terrestrial targets. The characteristics of directional effects are closely linked to the properties of the target and controlled by the view and solar geometry. A singular angular signature is obtained in the hotspot geometry, i.e., when the sun, the satellite and the target are aligned. The hotspot phenomenon highlights the temperature differences between sunlit and shaded areas. However, due to the lack of adequate multi-angle observations and inaccurate portrayal or neglect of solar influence, the hotspot effect is often overlooked and has become a barrier for better inversion results at satellite scale. Therefore, hotspot effect needs to be better characterized, which here is achieved with a three-component model that distinguishes vegetation, sunlit and shaded soil temperature components and accounts for vegetation structure. Our work combines thermal infrared (TIR) observations from the Sea and Land Surface Temperature Radiometer (SLSTR) onboard the LEO (Low Earth Orbit) Sentinel-3, and two sensors onboard GEO (geostationary) satellites, i.e. the Advanced Himawari Imager (AHI) and Spinning Enhanced Visible and Infrared Imager (SEVIRI). Based on inversion with a Bayesian method and prior information associated with component temperature differences as constrained, the findings include: 1) Satellite observations throughout East Asia around noon indicate that for every 10 degrees change in angular distance from the sun, LST will on average vary by 0.6 K; 2) As a better constraint, the hotspot effect can benefit from multi-angle TIR observations to improve the retrieval of LST components, thereby reducing the root mean squared error (RMSE) from approximately 3.5 K, 5.8 K, and 4.1 K to 2.8 K, 3.5 K, and 3.1 K, at DM, EVO and KAL sites, respectively; 3) Based on a dataset simulated with a threedimensional radiative transfer model, a significant inversion error may result if the hotspot is ignored for an angular distance between the viewing and solar directions that is smaller than 30 degrees. Overall, considering the hotspot effect has the potential to reduce inversion noise and to separate the temperature difference between sunlit and shaded areas in a pixel, paving the way for producing stable temperature component products.

Excessive phosphorus emissions can result in the eutrophication of water bodies, causing severe environmental damage as well as influencing the efficiency of water treatment equipment. The impacts of carbon/phosphorus ratios on performance and mechanism of the upflow anaerobic sludge bed reactor remain unclear. Henrie, the effects of different carbon/phosphorus ratios (i.e., 80:1, 40:1, and 20:1) on the transformation of phosphorus in the biological treatment process of an upflow anaerobic sludge blanket (UASB) reactor were studied. The results showed that phosphines are of great importance in the phosphate reduction process. After a stable operation, the phosphine reached the highest 81.91 mg/m3 at a C/P ratio of 40:1. It was proved that the optimum operating condition of the reactor was carbon to phosphorus ratio of 40:1. Phosphate-reducing bacteria were present in the UASB reactor, and the relative abundance of Clostridia in the sludge was 1.90 % and 1.59 % when the C/P was 80:1 and 20:1, respectively. This implied that the low carbon to phosphorus ratio reduces the phosphorusreducing microbial activity in the reactor. Lower C/P values could inhibit the uptake and use of P in the phosphonate transport system and the transport of phosphate in the cell by the microbial Pst system, impeding the mineralization of organophosphates. The study provides new insights into improving the efficiency of treating phosphorus-rich wastewater.