South and Southeast Asia (SSA) emitted black carbon (BC) exerts potential effects on glacier and snow melting and regional climate change in the Tibetan Plateau. In this study, online BC measurements were conducted for 1 year at a remote village located at the terminus of the Mingyong Glacier below the Meili Snow Mountains. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) was used to investigate the contribution and potential effect of SSA -emitted BC. In addition, variations in the light absorption characteristics of BC and brown carbon (BrC) were examined. The results indicated that the annual mean concentration of BC was 415 +/- 372 ngm(-3) , with the highest concentration observed in April (monthly mean: 930 +/- 484 ngm(-3) ). BC exhibited a similar diurnal variation throughout the year, with two peaks observed in the morning (from 8:00 to 9:00 AM) and in the afternoon (from 4:00 to 5:00 PM), with even lower values at nighttime. At a short wavelength of 370 nm, the absorption coefficient ( b abs ) reached its maximum value, and the majority of b abs values were < 20 Mm(-1) , indicating that the atmosphere was not overloaded with BC. At the same wavelength, BrC substantially contributed to b abs , with an annual mean of 25.2 % +/- 12.8 %. SSA was the largest contributor of BC (annual mean: 51.1 %) in the study area, particularly in spring (65.6 %). However, its contributions reached 20.2 % in summer, indicating non -negligible emissions from activities in other regions. In the atmosphere, the SSA BC -induced radiative forcing (RF) over the study region was positive. While at the near surface, the RF exhibited a significant seasonal variation, with the larger RF values occurring in winter and spring. Overall, our findings highlight the importance of controlling BC emissions from SSA to protect the Tibetan Plateau against pollution -related glacier and snow cover melting.

PM2.5 samples (n = 34) were collected from January to April 2017 over Shillong (25.7 degrees N, 91.9 degrees E; 1064 m amsl), a high-altitude site situated in the northeastern Himalaya. The main aim was to understand the sources, characteristics, and optical properties of local vs long-range transported carbonaceous aerosols (CA) using chemical species and dual carbon isotopes (13C and 14C). Percentage biomass burning (BB)/biogenic fraction (fbio, calculated from 14C) varied from 67 to 92 % (78 +/- 7) and correlated well with primary BB tracers like f60, and K+, suggesting BB as a considerable source. Rain events are shown to reduce the fbio fraction, indicating majority of BB-derived CA are transported. Further, delta 13C (-26.6 +/- 0.4) variability was very low over Shillong, suggesting it's limitations in source apportionment over the study region, if used alone. Average ratio of absorption coefficient of methanol-soluble BrC (BrCMS) to water-soluble BrC (BrCWS) at 365 nm was 1.8, indicating a significant part of BrC was water-insoluble. A good positive correlation between fbio and mass absorption efficiency of BrCWS and BrCMS at 365 nm with the higher slope for BrCMS suggests BB derived water-insoluble BrC was more absorbing. Relative radiative forcing (RRF, 300 to 2500 nm) of BrCWS and BrCMS with respect to EC were 11 +/- 5 % and 23 +/- 16 %, respectively. Further, the RRF of BrCMS was up to 60 %, and that of BrCWS was up to 22 % with respect to EC for the samples with fbio >= 0.85 (i.e., dominated by BB), reflecting the importance of BB in BrC RRF estimation.

The Indo-Gangetic Plain (IGP) is a major regional and global emitter of atmospheric pollutants, which adversely affect surrounding areas such as the Himalayas. We present a comprehensive dataset on carbonaceous aerosol (CA) composition, radiocarbon (D14C) -based source apportionment, and light absorption of total suspended particle (TSP) samples collected over a 3--year period from high-altitude Jomsom in the central Himalayas. The 3-year mean TSP, organic carbon (OC), and elemental carbon (EC) concentrations were 92.0 +/- 28.6, 9.74 +/- 6.31, and 2.02 +/- 1.35 lg m-3, respectively, with the highest concentrations observed during the pre-monsoon season, followed by the post-monsoon, winter, and monsoon seasons. The D14C analysis revealed that the contribution of fossil fuel combustion (ffossil) to EC was 47.9% +/- 11.5%, which is consistent with observations in urban and remote regions in South Asia and attests that EC likely arrives in Jomsom from upwind IGP sources via long-range transport. In addition, the lowest ffossil (38.7% +/- 13.3%) was observed in winter, indicating large contributions in this season from local biomass burning. The mass absorption cross- of EC (MACEC: 8.27 +/- 1.76 m2/g) and watersoluble organic carbon (MACWSOC: 0.98 +/- 0.45 m2/g) were slightly higher and lower than those reported in urban regions, respectively, indicating that CA undergo an aging process. Organic aerosol coating during transport and variation of biomass burning probably led to the seasonal variation in MAC of two components. Overall, WSOC contributed considerably to the light absorption (11.1% +/- 4.23%) of EC. The findings suggest that to protect glaciers of the Himalayas from pollution-related melting, it is essential to mitigate emissions from the IGP.(c) 2022 China University of Geosciences (Beijing) and Peking University. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/ licenses/by-nc-nd/4.0/).

The Pan-Third Pole contains the largest number of glaciers outside the polar region that plays a crucial role in atmospheric circulation and the hydrological cycle. However, this pristine region has undergone rapid change through complex interactions including the black carbon (BC) enhanced warming effect and glacier melting. Study shows, Weather Research and Forecasting coupled with Chemistry (WRF-Chem) simulation is able to capture distinctive seasonal variability of BC. The result from our sensitivity experiments revealed that South Asia (SA; 60.7%) and East Asia (EA; 32.9%) contributed more toward the Tibetan Plateau (TP). Our analysis on aerosol-boundary feedback interaction revealed BC expand planetary boundary layer height by 5.0% and 4.8% over SA and EA, respectively, which facilitates BC dispersion and transportation. Whereas, we also found that under the influence of different wind regimes the significant BC transport flux aloft over the TP and the upper troposphere and lower stratosphere. Additionally, mountain-valley channel and synoptic and local meteorological processes also facilitated BC transport to the TP. This study also evaluated the effect of BC on direct radiative forcing and calculated subsequent temperature changes. A strong dimming effect of BC corroborated with the following negative surface temperature changes. However, enhanced BC concentration during winter and spring caused the increase in temperature over the TP. Here, the WRF-Chem model, synergy on aerosol-boundary feedback, BC transport flux, and source-receptor methods confirmed the significant BC contribution and transportation, and notable BC-induced warming over TP. Such trans-Himalayan BC transport and associated warming could grim glacier melt and water availability in the region.

South and Southeast Asia (SSA) emitted black carbon (BC) exerts potential effects on glacier and snow melting and regional climate change in the Tibetan Plateau. In this study, online BC measurements were conducted for 1 year at a remote village located at the terminus of the Mingyong Glacier below the Meili Snow Mountains. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) was used to investigate the contribution and potential effect of SSA -emitted BC. In addition, variations in the light absorption characteristics of BC and brown carbon (BrC) were examined. The results indicated that the annual mean concentration of BC was 415 +/- 372 ngm(-3) , with the highest concentration observed in April (monthly mean: 930 +/- 484 ngm(-3) ). BC exhibited a similar diurnal variation throughout the year, with two peaks observed in the morning (from 8:00 to 9:00 AM) and in the afternoon (from 4:00 to 5:00 PM), with even lower values at nighttime. At a short wavelength of 370 nm, the absorption coefficient ( b abs ) reached its maximum value, and the majority of b abs values were < 20 Mm(-1) , indicating that the atmosphere was not overloaded with BC. At the same wavelength, BrC substantially contributed to b abs , with an annual mean of 25.2 % +/- 12.8 %. SSA was the largest contributor of BC (annual mean: 51.1 %) in the study area, particularly in spring (65.6 %). However, its contributions reached 20.2 % in summer, indicating non -negligible emissions from activities in other regions. In the atmosphere, the SSA BC -induced radiative forcing (RF) over the study region was positive. While at the near surface, the RF exhibited a significant seasonal variation, with the larger RF values occurring in winter and spring. Overall, our findings highlight the importance of controlling BC emissions from SSA to protect the Tibetan Plateau against pollution -related glacier and snow cover melting.

The Pan-Third Pole contains the largest number of glaciers outside the polar region that plays a crucial role in atmospheric circulation and the hydrological cycle. However, this pristine region has undergone rapid change through complex interactions including the black carbon (BC) enhanced warming effect and glacier melting. Study shows, Weather Research and Forecasting coupled with Chemistry (WRF-Chem) simulation is able to capture distinctive seasonal variability of BC. The result from our sensitivity experiments revealed that South Asia (SA; 60.7%) and East Asia (EA; 32.9%) contributed more toward the Tibetan Plateau (TP). Our analysis on aerosol-boundary feedback interaction revealed BC expand planetary boundary layer height by 5.0% and 4.8% over SA and EA, respectively, which facilitates BC dispersion and transportation. Whereas, we also found that under the influence of different wind regimes the significant BC transport flux aloft over the TP and the upper troposphere and lower stratosphere. Additionally, mountain-valley channel and synoptic and local meteorological processes also facilitated BC transport to the TP. This study also evaluated the effect of BC on direct radiative forcing and calculated subsequent temperature changes. A strong dimming effect of BC corroborated with the following negative surface temperature changes. However, enhanced BC concentration during winter and spring caused the increase in temperature over the TP. Here, the WRF-Chem model, synergy on aerosol-boundary feedback, BC transport flux, and source-receptor methods confirmed the significant BC contribution and transportation, and notable BC-induced warming over TP. Such trans-Himalayan BC transport and associated warming could grim glacier melt and water availability in the region.

Wildfire is a major source of biomass burning aerosols, which greatly impact Earth climate. Tree species in North America (NA) boreal forests can support high-intensity crown fires, resulting in elevated injection height and longer lifetime (on the order of months) of the wildfire aerosols. Given the long lifetime, the properties of aged NA wildfire aerosols are required to understand and quantify their effects on radiation and climate. Here we present comprehensive characterization of climatically relevant properties, including optical properties and cloud condensation nuclei (CCN) activities of aged NA wildfire aerosols, emitted from the record-breaking Canadian wildfires in August 2017. Despite the extreme injection height of similar to 12 km, some of the wildfire plumes descended into the marine boundary layer in the eastern North Atlantic over a period of similar to 2 weeks, owing to the dry intrusions behind mid-latitude cyclones. The aged wildfire aerosols have high single scattering albedos at 529 nm (omega(529); 0.92-0.95) while low absorption Angstrom exponents (angstrom(abs)) at 464 nm/648 nm (0.7-0.9). In comparison, angstrom(abs) of fresh/slightly aged ones are typically 1.4-3.5. This low angstrom(abs) indicates a nearly complete loss of brown carbon, likely due to bleaching and/or evaporation, during the long-range transport. The nearly complete loss suggests that on global average, direct radiative forcing of BrC may be minor. Combining Mie calculations and the measured aerosol hygroscopicity, volatility and size distributions, we show that the high omega(529) and low angstrom(abs) values are best explained by an external mixture of non-absorbing organic particles and absorbing particles of large BC cores (> similar to 110 nm diameter) with thick non-absorbing coatings. The accelerated descent of the wildfire plume also led to strong increase of CCN concentration at the supersaturation levels representative of marine low clouds. The hygroscopicity parameter, kappa(CCN), of the aged wildfire aerosols varies from 0.2 to 0.4, substantially lower than that of background marine boundary layer aerosols. However, the high fraction of particles with large diameter (i.e., within accumulation size ranges, similar to 100-250 nm) compensates for the low values of., and as a result, the aged NA wildfire aerosols contribute more efficiently to CCN population. These results provide direct evidence that the long-range transported NA wildfires can strongly influence CCN concentration in remote marine boundary layer, therefore the radiative properties of marine low clouds. Given the expected increases of NA wildfire intensity and frequency and regular occurrence of dry intrusion following mid-latitude cyclones, the influence of NA wildfire aerosols on CCN and clouds in remote marine environment need to be further examined.

This study was conducted in the Central Himalayan middle hills to understand the nature of polycyclic aromatic hydrocarbons (PAHs) embedded in aerosol particles, their sources and human health risk assessments. The level of sum of 15 particlephase PAHs was between 9 and 335 ng/m(3), with an average concentration of 73 +/- 66 ng/m(3). There were strong seasonal differences in total suspended particles (TSP) and particle-bound PAH concentrations with higher concentrations in winter, followed by premonsoon and lowest in monsoon. The main contributor to the suspended particles was 5-ring PAHs (32%), followed by 4-ring (29%), 6-ring (28%), and 3-ring PAHs (11%). Conversely, the gas-phase PAHs showed that 3-ring PAHs contributed utmost to the total particles. The molecular ratios and principal component analysis indicated that both petrogenic and pyrogenic sources, particularly fossil fuel combustion, biomass combustion, and car exhausts, were the major sources of PAHs. The overall average Benzo (a)pyrene equivalent concentration of particulate PAHs was 11.71 ng/m(3), which substantially exceeded the WHO guideline (1 ng/m(3)), and indicated the potential health risks for local residents. The average lifetime inhalation cancer risk (ILCR) estimates associated with carcinogenic PAHs was 8.78x 10(-6) for adults, suggesting the possible cancer risk and 2.47 x10(-5) for children, signifying extreme carcinogenic effects of PAHs on children's health. Therefore, strict measures should be taken to reduce PAHs emissions in the region.

An outflow of continental haze occurs from Indo-Gangetic Basin (IGB) in the North to Bay of Bengal (BoB) in the South. An integrated campaign was organized to investigate this continental haze during December 2013-February 2014 at source and remote regions within IGB to quantify its radiative effects. Measurements were carried out at three locations in eastern India; 1) Kalas Island, Sundarban (21.68 degrees N, 88.57 degrees E) - an isolated island along the north-east coast of BoB, 2) Kolkata (22.57 degrees N, 88.42 degrees E) - an urban metropolis and 3) Siliguri (26.70 degrees N, 88.35 degrees E) - an urban region at the foothills of eastern Himalayas. Ground-based AOD (at 0.5 mu m) is observed to be maximum (1.25 +/- 0.18) over Kolkata followed by Siliguri (0.60 +/- 0.17) and minimum over Sundarban (0.53 +/- 0.18). Black carbon concentration is found to be maximum at Kolkata (21.6 +/- 6.6 mu g . m(-3)) with almost equal concentrations at Siliguri (12.6 +/- 5.2 mu g . m(-3)) and Sundarban (12.3 +/- 3.0 mu g . m(-3)). Combination of MODIS-AOD and back-trajectories analysis shows an outflow of winter-time continental haze originating from central IGB and venting out through Sundarban towards BoB. This continental haze with high extinction coefficient is identified up to central BoB using CALIPSO observations and is found to contribute similar to 75% to marine AOD over central BoB. This haze produces significantly high aerosol radiative forcing within the atmosphere over Kolkata (75.4 Wm(-2)) as well as over Siliguri and Sundarban (40 Wm(-2)) indicating large forcing over entire IGB, from foothills of the Himalayas to coastal region. This winter-time continental haze also causes about similar radiative heating (1.5 K . day(-1)) from Siliguri to Sundarban which is enhanced over Kolkata (3 K . day(-1)) due to large emission of local urban aerosols. This high aerosol heating over entire IGB and coastal region of BoB can have considerable impact on the monsoonal circulation and more importantly, such haze transported over to BoB can significantly affect the marine hydrological cycle. (C) 2015 Elsevier B.V. All rights reserved.

PM2.5 carbonaceous particles were measured at Gosan, South Korea during 29 March-11 April 2002 which includes a pollution period (30 March-01 April) when the highest concentrations of major anthropogenic species (nss-SO4 (2-), NO3 (-), and NH4 (+)) were observed and a strong Asian dust (AD) period (08-10 April) when the highest concentrations of mainly dust-originated trace elements (Al, Ca, Mg, and Fe) were seen. The concentrations of elemental carbon (EC) measured in the pollution period were higher than those measured in the strong AD period, whereas an inverse variation in the concentrations of organic carbon (OC) was observed. Based on the OC/EC ratios, the possible source that mainly contributed to the highly elevated OC concentrations measured in the strong AD period was biomass burning. The influence of the long-range transport of smoke plumes emitted from regional biomass burning sources was evaluated by using MODIS (Moderate Resolution Imaging Spectroradiometer) satellite data for fire locations and the potential source contribution function analysis. The most potential source regions of biomass burning were the Primorsky and Amur regions in Far Eastern Russia and southeastern and southwestern Siberia, Russia. Further discussion on the source characteristics suggested that the high OC concentrations measured in the strong AD period were significantly affected by the smoldering phase of biomass burning. In addition to biomass burning, secondary OC (SOC) formed during atmospheric long-range transport should be also considered as an important source of OC concentration measured at Gosan. Although this study dealt with the episodic case of the concurrent increase of dust and biomass burning particles, understanding the characteristics of heterogeneous mixing aerosol is essential in assessing the radiative forcing of aerosol.