Light-absorbing carbonaceous aerosols, comprising black carbon (BC) and brown carbon (BrC), significantly influence air quality and radiative forcing. Unlike traditional approaches that use a fixed value of absorption & Aring;ngstrom exponent (AAE), this study investigated the absorption and optical properties of carbonaceous aerosols in Beijing for both local emission and regional transport events during a wintertime pollution event by using improved AAE results that employs wavelength-dependent AAE (WDA). By calculating the difference of BC AAE at different wavelengths using Mie theory and comparing the calculated results to actual measurements from an Aethalometer (AE31), a more accurate absorption coefficient of BrC can be derived. Through the analysis of air mass sources, local emission was found dominated the pollution events during this study, accounting for 81 % of all cases, while regional transport played a minor role. Carbonaceous aerosols exhibited a continuous increasing trend during midday, which may be attributed to the re-entrainment of nighttime-accumulated carbonaceous aerosols to the surface during the early planetary boundary layer (PBL) development phase, as the mixed layer rises, combined with the variation of PBL and anthropogenic activity. At night, variations in the PBL height, in addition to anthropogenic activities, effectively contributed to surface aerosol concentrations, leading to peak surface aerosol values during local pollution episodes. The diurnal variation of AAE470/880 exhibited a decreasing trend, with a total decrease of approximately 12 %. Furthermore, the BrC fraction showed a constant diurnal variation, suggesting that the declining AAE470/880 was primarily influenced by BC, possibly due to enhanced traffic contributions.

The long-term trend for aerosol optical properties and climate impact sensitivity in terms of radiative forcing efficiency were analyzed at a suburban station in Athens, Southeast Mediterranean, using an extensive dataset from 2008 to 2022. The study examined scattering (nsc) and absorption (nap) coefficients, scattering & Aring;ngstrom exponent (SAE), absorption & Aring;ngstrom exponent (AAE), single scattering albedo (SSA), asymmetry parameter (g), and radiative forcing efficiency (RFE). Seasonal variability was linked to meteorological conditions and human activities. Single Scattering Albedo (SSA) was lowest (0.86), and Radiative Forcing Efficiency (RFE) was highest (-61 W/m2) in winter, confirming enhanced contributions from traffic and biomass burning. Lower SAE values (1.5) in spring indicate a greater presence of coarse particles due to frequent Saharan dust events (SDEs). Daily patterns of nap and SSA reflect local emissions, with pronounced traffic-related peaks. Aerosol classification revealed that Black Carbon (BC) dominates the suburban aerosol (51 %), with mixed BrC-BC (16 %) peaking in winter and dust-pollution mixtures (13 %) increasing in spring. The presence of large particles mixed with BC (11 %) was more frequent in spring, further highlighting seasonal variability. Trend analysis showed statistically significant (ss) decreases in nsc (-0.611) and SSA (-0.003), alongside increases in nap (+0.027) and RFE (+0.270) at a 95 % confidence level, suggesting a shift toward more absorbing aerosols. The findings provide new insights and reveal a new aerosol regime, where a reduction in anthropogenic emissions is affecting the scattering rather than the absorbing aerosol component, while the impact from forest fires as a climate feedback mechanism has a significant effect in the Eastern Mediterranean. It is important for future studies and climate modelling to account for the regionally observed changes of the state of mixing of ambient aerosol leading to a shift in radiative forcing efficiency through the reduction in SSA. This is evident in the long term for the east Mediterranean region and must be accounted for in radiative forcing estimates and future climate projections.

Conventional materials necessitate a layer-by-layer rolling or tamping process for subgrade backfill projects, which hampers their utility in confined spaces and environments where compaction is challenging. To address this issue, a self-compacting poured solidified mucky soil was prepared. To assess the suitability of this innovative material for subgrade, a suite of performance including flowability, bleeding rate, setting time, unconfined compressive strength (UCS), and deformation modulus were employed as evaluation criteria. The workability and mechanical properties of poured solidified mucky soil were compared. The durability and solidification mechanism were investigated. The results demonstrate that the 28-day UCS of poured solidified mucky soil with 20% curing agent content reaches 2.54 MPa. The increase of organic matter content is not conducive to the solidification process. When the curing temperature is 20 degrees C, the 28-day UCS of the poured solidified mucky soil with curing agent content not less than 12% is greater than 0.8 MPa. The three-dimensional network structure formed with calcium silicate hydrate, calcium aluminate hydrate, and ettringite is the main source of strength formation. The recommended mud moisture content is not exceed 85%, the curing agent content is 16%, and the curing temperature should not be lower than 20 degrees C.

Deep-rooted maize plants utilize water and nutrients more effectively, particularly in compacted soil. However, the mechanisms by which different maize genotypes adjust root angles in response to compaction remain underexplored. We conducted a two-year study (2021-2022) on silty loam soils in the North China Plain. We tested two genotypes of maize [one with naturally deep roots (DR) and another with shallow roots (SR)] in compacted (C) and non-compacted (NC) soil. Soil compaction impeded shoot growth in both genotypes; however, DR exhibited better growth than SR. Under compacted conditions, DR maintained steeper root angles and demonstrated superior mechanical strength with larger root cortex areas (increased by 60 %) and stele (increased by 92 %), as well as higher cellulose concentration (up to 146 %). Notably, PIEZO1 gene expression increased significantly (up to 242 %) in DR under compaction, suggesting its role in root structural enhancement, unlike in SR where it remained unchanged. These findings underscore the importance of genetic, anatomical, and biochemical adaptations in maize roots, facilitating their resilience to soil compaction. Such insights could inform the breeding of maize genotypes that are better adapted to diverse soil conditions, potentially boosting agricultural productivity.

A comprehensive series of tests, including dynamic triaxial, monotonic triaxial and unconfined compressive strength (UCS) tests, were carried out on reconstituted landfill waste material buried for over twenty years in a closed landfill site in Sydney, Australia. Waste materials collected from the landfill site were treated with varying percentages of cement, and both treated and untreated specimens were investigated to evaluate the influence of cement treatment. The study examined the dynamic properties of cement-treated landfill waste, including cumulative plastic deformation, resilient modulus, and damping ratio, and also analysed the impact of cyclic loading on post-cyclic shear strength in comparison to pre-cyclic shear strength. The UCS tests and monotonic triaxial tests demonstrated that untreated specimens subjected to monotonic loading exhibited a progressive increase in strength with rising axial strain, whereas cement-treated specimens reached a peak strength before experiencing a decline. During cyclic loading, with the inclusion of cement, a significant reduction in cumulative plastic deformation and damping ratio was observed, and this reduction was further enhanced with increasing cement content. Conversely, the resilient modulus showed substantial improvement with the addition of cement, and this enhancement was further amplified with increasing cement content. The formation of cementation bonds between particles curtails particle movement within the landfill waste material matrix and prevents interparticle sliding during cyclic loading, leading to lower plastic strains and damping ratio while increasing resilient modulus. Post-cyclic monotonic testing revealed that cyclic loading caused the partial breakage of the cementation bonds, resulting in reduced shear strength. This reduction was higher on samples treated with lower cement content. Overall, the findings of the research offer crucial insights into the possibility of cement-treated landfill waste as a railway subgrade, laying the groundwork for informed design decisions in developing transport infrastructure over closed landfill sites while using landfill waste materials available on site.

The incorporation of PCMs in energy piles holds significant potential for revolutionising thermal management in construction, making them a crucial component in the development of next-generation systems. The existing literature on PCM-integrated energy piles largely consists of isolated case studies and experimental investigations, often focusing on specific aspects without providing a comprehensive synthesis to guide future research or practical applications. To date, no review has been conducted to consolidate and evaluate the existing knowledge on PCMs in energy piles, making this review the first of its kind in this field. Up until now, this gap in research has limited our understanding of how PCM configurations, thermal properties, and integration methods impact the thermal and mechanical performance of these systems. Through thoroughly analysing the current research landscape, this review discovers key trends, methodologies, and insights. The methodology used here involved a systematic search of the existing SCI/SCIE-indexed literature to ensure a structured review. Based on the SLR findings, it is evident that current research on PCMs in energy piles is focused on improving thermal efficiency, heat transfer, and compressive strength. Furthermore, precise adjustments in melting temperature significantly impact efficiency, with PCM integration boosting thermal energy extraction by up to 70 % in some cases, such as heating cycles, and saving up to 30 % in operational costs. PCMs also reduce soil temperature fluctuations, improving structural integrity through minimising axial load forces. However, challenges remain, including reduced mechanical strength due to voids and weak bonding, high costs, and complexities such as micro-encapsulation. We acknowledge that there are gaps in addressing certain key factors, including thermal diffusivity; volume change during phase transitions; thermal response time; compatibility with construction materials; interaction with soil, creep, and fatigue; material compatibility and durability; and the long-term energy savings associated with PCM-GEP systems.

Iron pipes connected by bell-spigot joints are utilized in buried pipeline systems for urban water and gas supply networks. The joints are the weak points of buried iron pipelines, which are particularly vulnerable to damage from excessive axial opening during seismic motion. The axial joint opening, resulting from the relative soil displacement surrounding the pipeline, is an important indicator for the seismic response of buried iron pipelines. The spatial variability of soil properties has a significant influence on the seismic response of the site soil, which subsequently affects the seismic response of the buried iron pipeline. In this study, two-dimensional finite element models of a generic site with explicit consideration of random soil properties and random mechanical properties of pipeline joints were established to investigate the seismic response of the site soil and the buried pipeline, respectively. The numerical results show that with consideration of the spatial variability of soil properties, the maximum axial opening of pipeline joints increases by at least 61.7 %, compared to the deterministic case. Moreover, in the case considering the variability of pipeline-soil interactions and joint resistance, the spatial variability of soil properties remains the dominant factor influencing the seismic response of buried iron pipelines.

The hydraulic effect of plant roots reduces precipitation infiltration and enhances shallow slope stability. However, after root death and decay, soil permeability increases while water-retention capacity decreases. The time-varying mechanisms governing the hydraulic properties of root-soil composites after root decay remain unclear. This study examines the evolution of soil pore structure following root decay. A time-varying soil water retention curve (SWRC) model was developed to characterize changes in water-retention capacity. Additionally, a time-varying saturated infiltration coefficient model and a permeability coefficient prediction model were established to describe variations in hydraulic properties. A one-dimensional soil column infiltration test was conducted on root-soil composites at different stages of root decay to investigate the time-dependent changes in hydraulic properties. The reliability of the proposed models was validated using experimental results. The findings indicate the following: After root death, root biomass, diameter, length, and number decreased with increasing decay time, stabilizing after four months. Root decay led to a reduction in root volume ratio, which altered soil structure and enhanced the permeability of root-soil composites. Longer decay periods increased soil porosity, modifying the soil water characteristic curve and reducing water-retention capacity. Creeping roots decayed more significantly than fibrous roots due to their distinct morphological traits, making changes in hydraulic properties more pronounced in the topsoil. Therefore, plant root decay negatively affects soil hydraulic properties by continuously altering soil pore structure. These findings provide a crucial foundation for understanding the time-dependent mechanisms of hydraulic property variations in root-soil composites during plant root decay.

Small modular reactors (SMRs) are an alternative for clean energy solutions in Canada's remote northern communities, owing to their safety, flexibility, and reduced capital requirements. Currently, these communities are heavily reliant on fossil fuels, and the transition to cleaner energy sources, such as SMRs, becomes imperative for Canada to achieve its ambitious net-zero emissions target by 2050. However, applying SMR technology in permafrost regions affected by climate change presents unique challenges. The degradation of permafrost can lead to significant deformations and settlements, which can result in increased maintenance expenses and reduced structural resilience of SMR infrastructure. In this paper, we studied the combined effect of climate nonstationarity in terms of ground surface temperature and heat dissipation from SMR reactor cores for the first time in two distinct locations in Canada's North: Salluit in Quebec and Inuvik in the Northwest Territories. It was shown that these combined effects can make significant changes to the ground thermal conditions within a radius of 15-20 m around the reactor core. The change in the ground thermal conditions poses a threat to the integrity of the permafrost table. The implementation of mitigation strategies is imperative to maintain the structural integrity of the nuclear infrastructure in permafrost regions. The thermal modeling presented in this study paves the way for the development of advanced coupled thermo-hydromechanical models to examine the impact of SMRs and climate nonstationarity on permafrost degradation.

This investigation examines the development of titanium slag-flue gas desulfurized gypsum-Portland cement ternary composites (the ternary composites) for the solidification and stabilization of Pb-contaminated soils. The efficacy of the ternary composites is systematically evaluated using a combination of experimental methodologies, including mechanical properties such as unconfined compressive strength, stress-strain behavior and elastic modulus, leaching toxicity, XRD, TG-DTG, FTIR, XPS, and SEM-EDS analyses. The results indicate that the mechanical properties of Portland cement solidified Pb-contaminated soils are inferior to those of Portland cement solidified Pb-free soil, both in the early and later stages. However, the mechanical properties of Pbcontaminated soils solidified by the ternary composites are superior to those of the ternary composites solidified Pb-free soils in the early stage but somewhat inferior in the later stage. The ternary composites significantly decrease the leached Pb concentrations of solidified Pb-contaminated soils, which somewhat increase with the Pb content and with the pH value decrease of the leaching agent. Moreover, with much lower carbon emissions index and strength normalized cost, the ternary composites have comparable stabilization effects on Pbcontaminated soils to Portland cement, suggesting that the ternary composites can serve as a viable alternative for the effective treatment of Pb-contaminated soils. Characterization via TG-DTG and XRD reveals that the primary hydration products of the ternary composite solidified Pb-contaminated soils include gypsum, ettringite, and calcite. Furthermore, FTIR, XPS and SEM-EDS analyses demonstrate that Pb ions are effectively adsorbed onto these hydration products and soil particles.