Tribochemically produced triboproducts are becoming increasingly important in tribosystems and serve to improve system performance by preventing friction or wear. Diamond-like carbon (DLC) is chemically stable, which features a trade-off with tribological pros and cons. Chemically stable DLC is thermally stable and suppresses surface damage in a high-temperature operating environment; however, it causes a detrimental effect that hinders the formation of a competent tribofilm. In this study, we dispersed highly reactive TiO 2 nanoparticles (TDONPs) in molybdenum dithiocarbamate (MoDTC)-containing lubricant for adhering triboproducts on the DLC surface. In addition, TDONPs contributed to the decomposition of triboproducts by promoting the decomposition of MoDTC through its catalytic role. Rutile TDONPs were more helpful in reducing friction than anatase TDONPs and improved the friction performance by up to ~100%.