The aim of this study was to identify the areal surface parameters that correlated with lowering of sliding friction. Different ground surfaces were created on stainless steel and the lubricated sliding friction generated at the contact interface with a flat-faced aluminum pin was studied. The frictional force encountered is an order of magnitude lower for a P1200-finished surface than the other ground surfaces. Using 3D surface profilometry, a unique surface parameter ratio “Spk/Sk” was found to predict the frictional performance of these surfaces. When this surface parameter ratio was less than 1, average sliding friction was close to 0.1. When this ratio was greater than 1, the coefficient was an order of magnitude lower. Using energy dispersive spectrometry, such surfaces after wear showed the presence of a uniform dispersed layer of iron oxide on the surface of the pin. This was absent on the surfaces having high friction, indicating the role of the steel counter surface in building this beneficial transfer layer. Scanning electron microscopy provided topography images to visualize the surface wear. The motivation for the authors was to use a commercially scaled process like precision grinding for the surface modifications on stainless steel.