The aerospace industry aims for net-zero greenhouse gas emissions by 2050, requiring gas turbine engines to reduce CO2 emissions. This will impact engine material selection due to harsher operating conditions, limiting traditional metal/alloy use. While fibre-reinforced polymers (FRP) composites are commonly used in the aerospace industry, their use in gas turbine engines is often restricted by the lower operating temperatures of the polymer matrix. However, many studies have demonstrated the tribological potential of FRP in the fan of the engines, but little attention has been given to the potential of orienting the fibers in the normal (i.e., out-of-plane) direction relative to the wear surface to leverage the anisotropic properties of FRP composites. This study aims to investigate the impact of fiber orientation on the tribological properties of carbon fiber/PEEK (CF-PEEK) at elevated temperatures. Three CF-PEEK samples with different fiber rientations were selected for the purpose of this study (parallel, anti-parallel and normal directions), as well as a fourth sample of pure PEEK. Tribological tests were conducted using a ball-on-disk tribometer at an elevated temperature of 200°C to evaluate wear and friction behavior. The worn surfaces and counterfaces were analyzed using confocal laser scanning microscopy (CLSM), scanning electron microscopy (SEM), and energy dispersive X-ray Spectroscopy (EDS). The findings reveal that CF-PEEK with fibers oriented in the normal direction demonstrates significantly enhanced tribological performance at elevated temperatures, achieving a 95% reduction in the friction coefficient and a 92% decrease in the wear rate compared to pure PEEK. A wear mechanism has been proposed to explain the superior wear resistance of normally oriented fibers in CF-PEEK, linking it to the development of a fiber-based interface during the run-in phase and the formation of a uniform transfer film.