Polyurea Coatings Based on a Dynamic Crosslinked Phase-Locked Network for Dynamic/Static Icing and Corrosion Protection

Surface icing and corrosion considerably reduce the operational safety of offshore wind turbines and can be mitigated through the use of lubricant-infused surfaces, which, however, often suffer from severe performance degradation under real-world conditions and lack long-term durability. Herein, this work prepares polyurea coatings based on a dynamic crosslinked phase-locked network and show that the alternating arrangement of strong and weak hydrogen bonds between the urea units facilitates the capture and storage of the liquid phase (silicone oil), while the affinity and associative interactions between this phase and polydimethylsiloxane segments ensure strong adhesion and integration. The best-performing coating exhibits good dynamic/static anti-icing properties (freezing delay time = 331 s, temperature of first ice nucleation = −24.6 °C, ice shear strength = 19.9 ± 3.3 kPa) according to the results of ice crystal growth simulations and wind tunnel tests while showing an exceptional anti-corrosion performance (low-frequency modulus (|Z|0.01 Hz) = 4.22 × 1010 Ω·cm2) and durability. Thus, this study presents a strategy for enhancing the ability of offshore wind turbines to withstand extreme environments and extending their service lifetimes.

相关文章

  • Lead carboxylates passivation for meter-scale perovskite solar modules
    [Dongdong Xu, Ke Xiao, Ye Liu, Xin Luo, Jian Xu, Yikang Wei, Yameen Ahmed, Shuncheng Yang, Haonan Liu, Yinke Wang, Shun Huang, Manya Li, Yuhong Zhang, Han Gao, Hongfei Sun, Gongtao Duan, Qiaolei Han, Qiang Liu, Shuo Zhang, Xingjie Lv, Jingfu Jiang, Li Chao, Dongxue Liu, Min Hao, Xincheng Hou, Makhsud I. Saidaminov, Hairen Tan]
  • Jammed interconnected bilayer emulsions as 3D-printable biological tissue mimics
    [Aida Fica, McKayla Torbett-Dougherty, Samuel West, Malika Rao, Raman Dhiman, Jun Wang, Yang Gao, Yu-Ming Tu, Harekrushna Behera, Claude Roc, Kyler Grogan, Alexandra Beaver, Chang Liu, Alexander Jui-An Lin, Brian Belardi, Benjamin K. Keitz, Robert J. Hickey, Zunlong Ke, Adrianne M. Rosales, Berkin Dortdivanlioglu, Stephen A. Sarles, Manish Kumar]
  • Effect of Unmelted Nanoparticles on the High-Temperature Tribological Performance of YSZ Abradable Sealing Coatings
    [Baixu Zhu, Wei Fan, Qi Liu, Zhicheng Yi, Yu Shi, Yi Zhang, Yu Bai]
  • qq

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ex

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    yx

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ph

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    广告图片

    润滑集