To address the severe wear issues of titanium alloys at elevated temperatures, CoCrFeNi-based high-entropy alloy (HEA) coatings were applied to the surface of titanium alloys using high-velocity oxygen fuel (HVOF) spraying. These CoCrFeNi-based HEA coatings significantly enhanced the tribological properties of the titanium alloys at both 500 °C and 700 °C. Notably, the MoCoCrFeNi coating exhibited optimal wear resistance, achieving a wear rate of only 2 × 10 -15 m 3 N -1 m -1 at 700 °C. This improvement can be attributed primarily to the formation of NiMoO 4 oxide films as a friction layer, which greatly enhances the friction-reducing properties, along with the high hardness of the MoCoCrFeNi coating, even at elevated temperatures.
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