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机械工程学会摩擦学分会固体润滑国家重点实验室摩擦学学报

二酯用于改善润滑剂组合物的抗磨性能的用途

专利摘要

本发明涉及下式(I)的二酯的用途: 右 a —C(O)—O—([C(R) 2 ] n ——O) s —C(O)—R b (我), 作为改善包含一种或多种抗磨损添加剂的润滑剂组合物的抗磨损性质的添加剂。 ......

基本信息

专利类型:
发明专利
申请/专利号:
US17/291118
申请日期:
2019-11-04
专利申请人:
分类号:
C10M169/04 ; C10M129/74 ; C10M141/10 ; C10N30/06 ; C10N40/25 ; C10N30/02
发明/设计人:
CHAMPAGNE, NICOLAS | ROBINEAU, GAËL
权利要求: 1. A method of improving the anti-wear properties of a lubricant composition comprising one or more anti-wear additives chosen from metal alkylthiophosphates, the method comprising adding to the lubricant composition an amount of a diester sufficient to improve the anti-wear properties of the composition,wherein the diester is represented by the following formula (I):Ra—C(O)—O—([C(R)2]n—O)s—C(O)—Rb (I),wherein:R represents, independently of one another, a hydrogen atom, or a linear or branched (C1-C5)alkyl group;s has a value of 1 or 2;n has a value of 1, 2 or 3, wherein when s is 2, n may be identical or different from s; andRa and Rb are independently selected from saturated or unsaturated, linear or branched, hydrocarbon-containing groups having a linear chain of 2 to 11 carbon atoms;with the provisos that:when s and n both have a value of 2, at least one of the R groups represents a linear or branched (C1-C5)alkyl group; andwhen s has a value of 1 and n has a value of 3, at least one of the R groups bound to the carbon in the beta position of the oxygen atoms of the ester functions represents a hydrogen atom,wherein the lubricant composition is of a grade according to the SAEJ300 classification defined by the formula (X)W(Y), wherein X represents 0 or 5; and Y represents an integer from 4 to 30,wherein the total amount of metal alkylthiophosphates in the composition ranges from 0.01 wt. % to 6 wt. %, relative to the total weight of the lubricant composition,wherein the total amount of diesters of formula (I) added to the lubricant composition ranges from 1 wt. % to 20 wt. %, relative to the total weight of the lubricant composition,wherein the anti-wear properties of the lubricant composition, evaluated according to a procedure based on standard ASTM D2670, are improved compared to a composition that is otherwise identical except for not comprising a diester of formula (l′), andwherein the lubricant composition comprises at least 50 wt. % of one or more base oils different from the diesters of formula (I).2. The method of claim 1, wherein the total amount of diesters of formula (I) added to the lubricant composition ranges from 5 wt. % to 20 wt. %, relative to the total weight of the lubricant composition.3. The method of claim 1, wherein the one or more anti-wear additives are selected from zinc dialkyldithiophosphates represented by the formula:Zn((SP(S)(OR)(OR′))2,wherein, R and R′ are independently selected from linear or branched alkyl groups comprising from 1 to 18 carbon atoms.4. The method of claim 1, wherein the lubricant composition comprises a total amount of metal alkylthiophosphates ranging from 0.1 wt. % to 2 wt. %, relative to the total weight of the lubricant composition.5. The method of claim 1, wherein the one or more base oils are oils of group II, Ill, or IV of the API classification.6. The method of claim 1, wherein the lubricant composition further comprises one or more of friction modifying additives, extreme pressure additives, detergents, antioxidants, viscosity index improvers, pour point depressants, dispersants, antifoaming agents, thickeners, or mixtures thereof.7. A method of improving the anti-wear properties of a lubricant composition comprising one or more anti-wear additives chosen from metal alkylthiophosphates, the method comprising adding to the lubricant composition an amount of a diester sufficient to improve the anti-wear properties of the composition,wherein the diester is represented by the following formula (I′):Ra—C(O)—O—([C(R)n—O)—([C(R′)2]m—O)s-1—C(O)—Rb (I′),wherein:R and R′ are independently selected from a hydrogen atom or a linear or branched (C1-C5)alkyl group;s has a value of 1 or 2;n has a value of 2;m has a value of 2; andRa and Rb are independently selected from saturated or unsaturated, linear or branched, hydrocarbon-containing groups having a linear chain of 2 to 11 carbon atoms;with the proviso that when s has a value of 2, at least one of the R or R′ groups represents a linear or branched (C1-C5)alkyl group,wherein the total amount of metal alkylthiophosphates in the composition ranges from 0.05 wt. % to 4 wt. %, relative to the total weight of the lubricant composition, andwherein the total amount of diesters of formula (I′) added to the lubricant composition ranges from 1 wt. % to 20 wt. %, relative to the total weight of the lubricant composition,wherein the anti-wear properties of the lubricant composition, evaluated according to a procedure based on standard ASTM D2670, are improved compared to a composition that is otherwise identical except for not comprising a diester of formula (r), andwherein the lubricant composition comprises at least 50 wt. % of one or more base oils different from the diesters of formula (I).8. The method of claim 7, wherein:s has a value of 2;one of the R groups represents a linear or branched (C1-C5)alkyl group and the other R group represents a hydrogen atom; andone of the R′ groups represents a linear or branched (C1-C5)alkyl group and the other R′ group represents a hydrogen atom.9. The method of claim 7, wherein:s has a value of 1, andone of the R groups represents a linear or branched (C1-C5)alkyl group and the other R group represents a hydrogen atom.10. The method of claim 7, wherein the total amount of diesters of formula (I′) added to the lubricant composition ranges from 5 wt. % to 20 wt. %, relative to the total weight of the lubricant composition.11. The method of claim 7, wherein the one or more anti-wear additives are selected from zinc dialkyldithiophosphates represented by the formula:Zn((SP(S)(OR)(OR′))2,wherein R and R′ are independently selected from linear or branched alkyl groups comprising from 1 to 18 carbon atoms.12. The method of claim 7, wherein the lubricant composition comprises a total amount of metal alkylthiophosphates ranging from 0.1 wt. % to 2 wt. %, relative to the total weight of the lubricant composition.13. The method of claim 7, wherein the one or more base oils are oils of group II, Ill, or IV of the API classification.14. The method of claim 7, wherein the lubricant composition is of a grade according to the SAEJ300 classification defined by the formula (X)W(Y), wherein X represents 0 or 5, and Y represents an integer from 4 to 30.15. The method of claim 7, wherein the lubricant composition further comprises one or more of friction modifying additives, extreme pressure additives, detergents, antioxidants, viscosity index improvers, pour point depressants, dispersants, antifoaming agents, thickeners, or mixtures thereof.16. The method of claim 1, wherein:the anti-wear additives comprise zinc dialkyldithiophosphate, andthe composition further comprises at least one polymethylacrylate polymer.