Nature-Inspired Incorporation of Precipitants into High-Strength Bulk Aluminum Alloys Enables Life-Long Extraordinary Corrosion Resistance in Diverse Aqueous Environments

The safe service and wide applications of lightweight high-strength aluminum alloys are seriously challenged by diverse environmental corrosion, since high strength and corrosion resistance are mutually exclusive for metals while surface protection cannot provide life-long corrosion resistance. Here, inspired by fish secreting slime from glands to resist external changes, a strategy of incorporating precipitants as the slime into bulk metals using the inner cavity of opened carbon nanotubes (CNTs) as the glands is developed to enable high-strength aluminum alloys with life-long superior corrosion resistance. The resulting material has ultrahigh tensile strength (≈700 MPa) and extraordinary corrosion resistance in acidic, neutral and alkaline media. Notably, it has the highest resistance to intergranular corrosion, exfoliation corrosion and stress-corrosion cracking, compared with all previously reported aluminum alloys, and its corrosion rate is even much lower than that of corrosion-resistant pure aluminum, which results from the pronounced surface enrichment of precipitants released (secreted) from exposed CNTs forming a protective surface film. Such high corrosion resistance is life-long and self-healing due to the on-demand minimal self-supply of the precipitants dispersed throughout the bulk material. This strategy can be readily expanded to other aluminum alloys, and could pave the way for developing corrosion-resistant high-strength metallic materials.

相关文章

  • Wafer-scale growth of highly stable p-type semiconducting monolayer MoSi2N4 single crystals
    [Su Sun, Chuan Xu, Keqiang Ji, Yuexing Xia, Bo Tong, Jinmeng Tong, Chen Chen, Wenqin Zhao, Duanliang Zhou, Qinghe Wang, Lixin Yang, Qiang Wang, Miaomiao Li, Biyuan Zheng, Lai-Peng Ma, Xinfeng Liu, Zhibo Liu, Mengjian Zhu, Kaihui Liu, Peng Liu, Kaili Jiang, Hui-Ming Cheng, Wencai Ren]
  • Low-surface-energy nanofillers for fast and selective Li+ transport toward stable solid-state lithium metal batteries
    [Jie Yang, Wenqiang Han, Yanfei Yang, La Zhuo, Junping Zhang]
  • Autonomous Self-Healing Anti-Corrosion Coating Enabled by Synergy of Hydrophobic Deep Eutectic Solvent and Elastic Resin
    [Chong Chen, Ting Shen, Jiahong Wei, Jie Yang, Wenkai Cao, Weihua Li]
  • qq

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ex

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    yx

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ph

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    广告图片

    润滑集