Triboelectric nanogenerators (TENGs) have gained significant attention for ability to convert mechanical energy into electrical energy. As the applications of TENG devices expand, their safety and reliability becomes priority, particularly where there is risk of fire or spontaneous combustion. Flame-retardant materials can be employed to address these safety concerns without compromising the performance and efficiency of TENGs. The primary focus of this review is on flame-retardant materials, including polymers, biomaterials, liquid polymers, aerogels, and carbon-based materials. The fundamental properties of these materials for TENG applications are elucidated. The characteristics of each material type are described, along with their potential to boost the safety and performance of TENGs. The importance of flame retardancy in advancing TENG technology can be projected from its usage in wearable electronics, self-powered sensors, and smart textiles. Current challenges such as material compatibility, fabrication complexity, and environmental concerns are addressed, along with proposed strategies for overcoming them. This review underscores the significance of flame-retardant materials in strengthening the functionality and safety of TENG devices, paving the way for their widespread adoption across various industries.