Perovskite–organic tandem solar cells with a photo-transformable stabilizer

Wide-bandgap (WBG) mixed-halide perovskites with high Br content, which are employed as the front cell material in perovskite–organic tandem solar cells (TSCs), often suffer from initial halide-mixing inhomogeneity and light-induced halide segregation1–3, limiting the performance of perovskite–organic TSCs. Here, we introduced a photo-transformable additive 4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzylamine (TDB) into the WBG perovskite precursor solution to establish a two-stage strategy for stabilizing the mixed-halide phase. During crystallization, TDB improves the initial halide homogeneity by suppressing the rapid precipitation of the Br-rich phase and accelerating halide mixing upon annealing. During operational illumination, TDB undergoes transformation to form a new species with stronger adsorption on the perovskite grain-boundary surfaces, which inhibits the formation of iodide-related defects, suppresses defect-assisted carrier trapping and ion migration, thereby mitigating light-induced halide segregation4–6. The representative WBG perovskite (Eg = 1.88 eV) solar cell achieved a power conversion efficiency (PCE) of 20.01%, with an open-circuit voltage of 1.42 V, a fill factor of 85.13% and improved stability under illumination. By integrating the WBG perovskite solar cell into a monolithic perovskite–organic TSC, we achieved a PCE of 28.80% with a certified steady-state PCE of 28.04%. The perovskite–organic TSC retained 90% of its initial PCE after 625 h of operation under the ISOS-L-1 protocol.

相关文章

  • Regional heterogeneity and collagen I/III quantification in human dura mater guide the design and tensile characterization of prototype patch
    [Kaiyang Zu, Jionghao Xue, Yicong Wang, Zhonghan Li, Jianping Gao, Yu Chen, Xi Luo, Lili Ju, Hao Wang]
  • Multi-scale investigation of hybrid fiber-reinforced concrete for mitigating early-age shrinkage cracking in bridge deck pavements
    [Hao-Ping Guo, Yu Chen, Meng-Ge Guo, Ling-Bo Wang, Peng Wang, Wen-Qi Wang, Jia-Hang Chen, Jing-Jie Wang, Zhan-Jiang Zhu, Ye Tian, Jia-Cheng Xu, Guo-Yi Zhang, Ke-Wei Yu, Meng-Bo Chen]
  • Reinforcement learning control of quantum error correction
    [Volodymyr Sivak, Alexis Morvan, Michael Broughton, Rodrigo G. Cortiñas, Johannes Bausch, Andrew W. Senior, Matthew Neeley, Alec Eickbusch, Noah Shutty, Laleh Aghababaie Beni, James S. Spencer, Francisco J. Heras, Thomas Edlich, Dmitry Abanin, Amira Abbas, Rajeev Acharya, Georg Aigeldinger, Ross Alcaraz, Sayra Alcaraz, Trond I. Andersen, Markus Ansmann, Frank Arute, Kunal Arya, Walt Askew, Nikita Astrakhantsev, Juan Atalaya, Brian Ballard, Joseph C. Bardin, Hector Bates, Andreas Bengtsson, Majid Bigdeli Karimi, Alexander Bilmes, Simon Bilodeau, Felix Borjans, Alexandre Bourassa, Jenna Bovaird, Dylan Bowers, Leon Brill, Peter Brooks, David A. Browne, Brett Buchea, Bob B. Buckley, Tim Burger, Brian Burkett, Nicholas Bushnell, Jamal Busnaina, Anthony Cabrera, Juan Campero, Hung-Shen Chang, Silas Chen, Ben Chiaro, Liang-Ying Chih, Agnetta Y. Cleland, Bryan Cochrane, Matt Cockrell, Josh Cogan, Roberto Collins, Paul Conner, Harold Cook, William Courtney, Alexander L. Crook, Ben Curtin, Martin Damyanov, Sayan Das, Dripto M. Debroy, Sean Demura, Paul Donohoe, Ilya Drozdov, Andrew Dunsworth, Valerie Ehimhen, Aviv Moshe Elbag, Lior Ella, Mahmoud Elzouka, David Enriquez, Catherine Erickson, Vinicius S. Ferreira, Marcos Flores, Leslie Flores Burgos, Ebrahim Forati, Jeremiah Ford, Austin G. Fowler, Brooks Foxen, Masaya Fukami, Alan Wing Lun Fung, Lenny Fuste, Suhas Ganjam, Gonzalo Garcia, Christopher Garrick, Robert Gasca, Helge Gehring, Robert Geiger, Élie Genois, William Giang, Dar Gilboa, James E. Goeders, Edward C. Gonzales, Raja Gosula, Stijn J. de Graaf, Alejandro Grajales Dau, Dietrich Graumann, Joel Grebel, Alex Greene, Jonathan A. Gross, Jose Guerrero, Loïck Le Guevel, Tan Ha, Steve Habegger, Tanner Hadick, Ali Hadjikhani, Michael C. Hamilton, Matthew P. Harrigan, Sean D. Harrington, Jeanne Hartshorn, Stephen Heslin, Paula Heu, Oscar Higgott, Reno Hiltermann, Hsin-Yuan Huang, Mike Hucka, Christopher Hudspeth, Ashley Huff, William J. Huggins, Evan Jeffrey, Shaun Jevons, Zhang Jiang, Xiaoxuan Jin, Chaitali Joshi, Pavol Juhas, Andreas Kabel, Dvir Kafri, Hui Kang, Kiseo Kang, Amir H. Karamlou, Ryan Kaufman, Kostyantyn Kechedzhi, Tanuj Khattar, Mostafa Khezri, Seon Kim, Can M. Knaut, Bryce Kobrin, Fedor Kostritsa, John Mark Kreikebaum, Ryuho Kudo, Ben Kueffler, Arun Kumar, Vladislav D. Kurilovich, Vitali Kutsko, Nathan Lacroix, David Landhuis, Tiano Lange-Dei, Brandon W. Langley, Pavel Laptev, Kim-Ming Lau, Justin Ledford, Joy Lee, Kenny Lee, Brian J. Lester, Wendy Leung, Lily Li, Wing Yan Li, Ming Li, Alexander T. Lill, William P. Livingston, Matthew T. Lloyd, Aditya Locharla, Laura De Lorenzo, Daniel Lundahl, Aaron Lunt, Sid Madhuk, Aniket Maiti, Ashley Maloney, Salvatore Mandrá, Leigh S. Martin, Orion Martin, Eric Mascot, Paul Masih Das, Dmitri Maslov, Melvin Mathews, Cameron Maxfield, Jarrod R. McClean, Matt McEwen, Seneca Meeks, Kevin C. Miao, Zlatko K. Minev, Reza Molavi, Sebastian Molina, Shirin Montazeri, Charles Neill, Michael Newman, Anthony Nguyen, Murray Nguyen, Chia-Hung Ni, Murphy Yuezhen Niu, Logan Oas, Raymond Orosco, Kristoffer Ottosson, Alice Pagano, Agustin Di Paolo, Sherman Peek, David Peterson, Alex Pizzuto, Elias Portoles, Rebecca Potter, Orion Pritchard, Michael Qian, Chris Quintana, Arpit Ranadive, Matthew J. Reagor, Rachel Resnick, David M. Rhodes, Daniel Riley, Gabrielle Roberts, Roberto Rodriguez, Emma Ropes, Lucia B. De Rose, Eliott Rosenberg, Emma Rosenfeld, Dario Rosenstock, Elizabeth Rossi, Pedram Roushan, David A. Rower, Robert Salazar, Kannan Sankaragomathi, Murat Can Sarihan, Kevin J. Satzinger, Max Schaefer, Sebastian Schroeder, Henry F. Schurkus, Aria Shahingohar, Michael J. Shearn, Aaron Shorter, Vladimir Shvarts, Spencer Small, W. Clarke Smith, David A. Sobel, Barrett Spells, Sofia Springer, George Sterling, Jordan Suchard, Aaron Szasz, Alexander Sztein, Madeline Taylor, Jothi Priyanka Thiruraman, Douglas Thor, Dogan Timucin, Eifu Tomita, Alfredo Torres, M. Mert Torunbalci, Hao Tran, Abeer Vaishnav, Justin Vargas, Sergey Vdovichev, Guifre Vidal, Catherine Vollgraff Heidweiller, Meghan Voorhees, Steven Waltman, Jonathan Waltz, Shannon X. Wang, Brayden Ware, James D. Watson, Yonghua Wei, Travis Weidel, Theodore White, Kristi Wong, Bryan W. K. Woo, Christopher J. Wood, Maddy Woodson, Cheng Xing, Z. Jamie Yao, Ping Yeh, Bicheng Ying, Juhwan Yoo, Noureldin Yosri, Elliot Young, Grayson Young, Adam Zalcman, Ran Zhang, Yaxing Zhang, Ningfeng Zhu, Nicholas Zobrist, Zhenjie Zou, Ryan Babbush, Dave Bacon, Sergio Boixo, Yu Chen, Zijun Chen, Michel Devoret, Monica Hansen, Jeremy Hilton, Cody Jones, Julian Kelly, Alexander N. Korotkov, Erik Lucero, Anthony Megrant, Hartmut Neven, William D. Oliver, Ganesh Ramachandran, Vadim Smelyanskiy, Paul V. Klimov]
  • qq

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ex

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    yx

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    ph

    成果名称:低表面能涂层

    合作方式:技术开发

    联 系 人:周老师

    联系电话:13321314106

    广告图片

    润滑集