High molecular weight, oil-soluble, mono- and polycarboxylic acid esters are posttreated with mono- or polycarboxylic acid acylating reagents to provide compositions useful as dispersants in lubricants and fuels. Esters of polyisobutenyl-substituted succinic anhydride and pentaerythritol posttreated with maleic anhydride exemplify the process and compositions of this invention.
The present invention is directed to the use of cyclic amide alkoxylate compounds as additives in fuel compositions having a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of one or more cyclic amide alkoxylate compounds of the formula:(I) wherein x is from 2 to 20 and y is from 1 to 50. R1 and R2 are independently hydrogen or hydrocarbyl of 1 to 100 carbon atoms. R3 is hydrocarbyl of 1 to 100 carbon atoms and R4 is independently hydrocarbyl of 2 to 100 carbon atoms. R5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms. The invention is also directed to the use of these cyclic amide alkoxylate compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to novel cyclic amide alkoxylate compounds.
Disclosed herein are additives which are useful as dispersants and detergents in lubricating oils and fuels. In particular, this invention is directed toward polyamino alkenyl or alkyl succinimides wherein one or more of the amino nitrogens of the succinimide is substituted withwherein R4 is hydrocarbyl of from 1 to 30 carbon atoms; R5 is hydrocarbyl of from 2 to 30 carbon atoms or 13 R6-(OR6)p- wherein R6 is alkylene of 2 to 5 carbon atoms and p is an integer from 1 to 100; and m is an integer of from 0 to 1.
Disclosed herein are additives which are useful as dispersants and detergents in lubricating oils and fuels. In particular, this invention is directed toward polyamino alkenyl or alkyl succinimides wherein one or more of the amino nitrogens of the succinimide is converted to
C5-C9 lactone based adduct materials are made by reacting a C5-C9 lactone with a polyamine, a polyol or an amino alcohol to form a lactone adduct intermediate, and thereafter reacting the intermediate with an aliphatic hydrocarbyl saturated or unsaturated, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about one to about 165 total carbon atoms in said straight or branched chain to insure that the resulting lactone adduct is hydrocarbon soluble. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.
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Disclosed herein are additives which are useful as dispersants and detergents in lubricating oils and fuels. In particular, this invention is directed toward polyamino alkenyl or alkyl succinimides wherein one or more of the amino nitrogens of the succinimide is substituted withwherein R4 is hydrocarbyl of from 1 to 30 carbon atoms; R5 is hydrocarbyl of from 2 to 30 carbon atoms or -R6-(OR6)p- wherein R6 is alkylene of 2 to 5 carbon atoms and p is an integer from 1 to 100; and m is an integer of from 0 to 1.
Combinations of dimercaptothiadiazole-mercaptan coupled derivatives with amines have been found to be effective load-carrying additives for lubricants and fuels.
A process for post-treating oil-soluble esters of mono- or polycarboxylic acids and polyhydric alcohols with organic epoxides. The acyl moiety of the esters is derived from mono- or polycarboxylic acids containing at least about fifty aliphatic carbon atoms exlusive of the carboxyl carbon atoms. The products are useful as lubricant and fuel additives. A typical example of the process would be the post-treatment of a diester of polyisobutenyl1-substituted succinic acid and sorbitol with propylene oxide.
A fuel composition is disclosed which comprises (A) at least one low sulfur diesel fuel; and (B) esters from the transesterification of at least one animal fat or vegetable oil triglyceride of the formulawherein R1, R2 and R3 are aliphatic hydrocarbyl groups having at least 60 percent monounsaturated character and containing from about 6 to about 24 carbon atoms with an alcohol or phenol R4OH wherein R4 is an aliphatic group containing from 1 to about 22 carbon atoms or an aromatic or substituted aromatic group containing from 6 to about 50 carbon atoms.